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	Efficient preconcentration of ultra-trace rhenium from geological materials via induced adsorption for accurate isotope analysis
通讯作者	Chen, Tianyu([email protected])
	Liu, Yumeng1; Chen, Tianyu1; Li, Tao2; Li, Weiqiang1; Hong, Qingquan1; Chen, Jiubin3
	2024-09-30
发表期刊	JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY
ISSN	0267-9477
页码	8
摘要	Rhenium (Re) and its isotopes offer valuable information for understanding various geological processes throughout Earth's history. However, Re isotope analysis remains quite challenging owing to its ultra-trace concentration in geological materials. Previous studies have developed column chemistry and analytical methods for Re isotope analysis, but issues such as tedious pretreatment and incomplete Re recovery still exist. Herein, we present a novel procedure integrating preconcentration and fast column chemistry for Re isotope analysis. Utilizing Na2S solution and activated carbon powder under acidified conditions, we achieved the quantitative recovery of Re from aqueous solutions via filtration while removing most matrices. Standard addition to diverse matrix solutions yielded complete Re recovery (99.6 +/- 6.7%, n = 10, 2SD) and precise isotopic compositions (delta Re-187 = -0.49 +/- 0.04 parts per thousand, n = 10, 2SD), as determined using multi-collector inductively coupled plasma-mass spectrometry. Our method was applied to seawater (7.1 pg g(-1) for Re) and solid reference materials (similar to 0.5-75 ng g(-1) for Re), which resulted in stable and high recovery with isotopic results consistent with published data. Our method exhibits efficient matrix removal with stable and essentially quantitative Re recovery, which paves the way for wide applications of Re isotopes in the earth and planetary sciences.
DOI	10.1039/d4ja00295d
收录类别	SCI
语种	英语
关键词[WOS]	INTERSPECIES ELECTRON-TRANSFER ; COMPARATIVE GEOCHEMISTRY ; COPRECIPITATION METHOD ; TUNGSTEN SPECIATION ; SULFIDIC WATERS ; MOLYBDENUM ; CARBON ; SEQUESTRATION ; CHALCOPHILE ; ENRICHMENTS
资助项目	National Natural Science Foundation of China[42361144845] ; National Natural Science Foundation of China[92358301] ; National Natural Science Foundation of China[41991325] ; National Natural Science Foundation of China
WOS研究方向	Chemistry ; Spectroscopy
WOS类目	Chemistry, Analytical ; Spectroscopy
WOS记录号	WOS:001325094000001
项目资助者	National Natural Science Foundation of China ; National Natural Science Foundation of China
出版者	ROYAL SOC CHEMISTRY
文献类型	期刊论文
条目标识符	http://ir.nigpas.ac.cn/handle/332004/44362
专题	中国科学院南京地质古生物研究所
通讯作者	Chen, Tianyu
作者单位	1.Nanjing Univ, Frontiers Sci Ctr Crit Earth Mat Cycling, Sch Earth Sci & Engn, State Key Lab Mineral Deposits Res, Nanjing 210046, Peoples R China 2.Chinese Acad Sci, State Key Lab Palaeobiol & Stratig, Nanjing Inst Geol & Palaeontol, Nanjing 210008, Peoples R China 3.Tianjin Univ, Inst Surface Earth Syst Sci, Sch Earth Syst Sci, Tianjin 300072, Peoples R China
推荐引用方式 GB/T 7714	Liu, Yumeng,Chen, Tianyu,Li, Tao,et al. Efficient preconcentration of ultra-trace rhenium from geological materials via induced adsorption for accurate isotope analysis[J]. JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY,2024:8.
APA	Liu, Yumeng,Chen, Tianyu,Li, Tao,Li, Weiqiang,Hong, Qingquan,&Chen, Jiubin.(2024).Efficient preconcentration of ultra-trace rhenium from geological materials via induced adsorption for accurate isotope analysis.JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY,8.
MLA	Liu, Yumeng,et al."Efficient preconcentration of ultra-trace rhenium from geological materials via induced adsorption for accurate isotope analysis".JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY (2024):8.

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